Gold-catalysed alkenyl- and arylsilylation reactions forming 1-silaindenes

作者:Matsuda Takanori*; Yamaguchi Yoshiyuki; Shigeno Masanori; Sato Shinya; Murakami Masahiro
来源:Chemical communications, 2011, 47(30): 8697-8699.
DOI:10.1039/c1cc12457a

摘要

In the presence of gold(I)-phosphine catalysts, alkenyl- and arylsilanes undergo intramolecular cyclisation reactions onto appendant alkyne moieties to afford 1-silaindene derivatives. The reaction pathways vary depending on the substituent on silicon.

  • 出版日期2011