A non-interpenetrating 3D porous metal-organic framework (MOF) holding rutile-type topology containing Cu-4 secondary building units

作者：Sun Gong ming; Feng Xue feng; Huang Hai xiao; Liao Zhen wei; Song Yu mei; Tian Xiao zhao; Liu Shu juan; Luo Feng^*

来源：Inorganic Chemistry Communications, 2012, 16: 43-46.

DOI：10.1016/j.inoche.2011.11.026

• Porous MOFs
• Cu-4 secondary building units
• Rutile
• Solvo(hydro)thermal method

In this work, we obtained a rarely three-dimensional porous Cu(II) MOF, namely [Cu-2(BTC)(OH)(Me2NH)center dot 2H(2)O center dot DMF](n) (Me2NH-dimethylamine, [BTC-3-1,3,5-benzenetricarboxylate, DMF-N,N'-dimethylformamide], by solvo(hydro)thermal method. This polymer was characterized by single-crystal X-ray diffraction, EA, and thermogravimetry analysis. The outstanding structural feature of it is the coordination of Me2NH-a hydrolysate from DMF, and the non-interpenetrating porous rutile net. Further, based on the investigation of literatures, we also discussed the architectonics involving common Cu-4 secondary building unit (SBU) in detail.

• 出版日期2012-2
• 单位东华理工大学