Alkyne-Substituted N-Heterophenes

作者:Hahn Sebastian; Koser Silke; Hodecker Manuel; Tverskoy Olena; Rominger Frank; Dreuw Andreas; Bunz Uwe H F*
来源:Chemistry - A European Journal, 2017, 23(34): 8148-8151.
DOI:10.1002/chem.201701304

摘要

The synthesis and characterization of novel S-shaped N-heterophenes is reported. The targets contain a central anthracene connected to two heterophenanthrene units. N-Heterophenes are synthesized by reacting Boldt's 1,2,6,7-anthracenetetraone with different dialkynylated ortho-diaminobenzenes. The condensation yields range from 63 to 75%; all of the N-heterophenes are stable and isolable.

  • 出版日期2017-6-16