Modification of Activated Carbon Using Nitration Followed by Reduction for Carbon Dioxide Capture

作者：Shafeeyan Mohammad Saleh; Houshmand Amirhossein^*; Arami Niya Arash; Razaghizadeh Hosain; Daud Wan Mohd Ashri Wan

来源：Bulletin of the Korean Chemical Society, 2015, 36(2): 533-538.

DOI：10.1002/bkcs.10100

• Activated carbon
• Surface modification
• Anchoring
• Amino groups
• Nitration

Activated carbon (AC) samples were modified using nitration followed by reduction to enhance their CO2 adsorption capacities. Besides characterization of the samples, investigation of CO2 capture performance was conducted by CO2 isothermal adsorption, temperature-programmed (TP) CO2 adsorption, cyclic CO2 adsorption-desorption, and dynamic CO2 adsorption tests. Almost all modified samples showed a rise in the amount of CO2 adsorbed when the comparison is made in unit surface area. On the other hand, some of the samples displayed a capacity superior to that of the parent material when compared in mass unit, especially at elevated temperatures. Despite similar to 65% decrease in the surface area, TP-CO2 adsorption of the best samples exhibited increases of similar to 10 and 70% in CO2 capture capacity at 30 and 100 degrees C, respectively.

• 出版日期2015-2