Axial chirality control of tropos BIPHEP-Rh complexes by chiral dienes: synergy effect in catalytic asymmetric hydrogenation

作者：Aikawa Kohsuke; Takabayashi Yuki; Kawauchi Susumu; Mikami Koichi^*

来源：Chemical communications, 2008, (41): 5095-5097.

DOI：10.1039/b809683j

Diastereopure tropos Rh complexes bearing not only BIPHEP but also chiral dienes can be employed as highly enantioselective hydrogenation catalysts for an olefinic substrate.

• 出版日期2008