Mild, green copper/4-dimethylaminopyridine catalysed aerobic oxidation of alcohols mediated by nitroxyl radicals in water

作者：Zhang Guoqi^*; Yang Chengxiong; Liu E; Li Li; Golen James A; Rheingold Arnold L

来源：RSC Advances, 2014, 4(106): 61907-61911.

DOI：10.1039/c4ra13929a

A novel copper/4-dimethylaminopyridine catalyst system has been found to catalyse the aerobic oxidation of a variety of primary and secondary alcohols in water at room temperature, in the presence of a TEMPO or ABNO nitroxyl radical. A tetranuclear Cu-II cluster was revealed to be a plausible reactive intermediate.

• 出版日期2014
• 单位荆楚理工学院