Acetonitrile-kappa N) (2,2 ': 6 ',2 ''-terpyridyl-kappa N-3)palladium(II)]bis(hexafluoro-phosphate)

作者：Mei Guang Quan^*; Huang Ke Long

来源：Acta Crystallographica Section E-Structure Reports Online, 2007, 63: M2029-U83.

DOI：10.1107/S160053680703070X

In the title compound, [Pd(C15H11N3)(C2H3N)](PF6)(2), the Pd atom is four-coordinated by a tridentate chelating 2,2':6',12 ''-terpyridine ligand and an acetonitrile ligand in a square-planar geometry. The cations and hexafluoridophosphate anions are connected together via anion-pi interactions [P-F center dot center dot center dot pi = 3.063 (5) and 3.076 (6) angstrom] and C-H center dot center dot center dot F hydrogen bonds to form alternating layers along the b axis.

• 出版日期2007-8
• 单位中南大学