Antibiotic removal from water: A highly efficient silver phosphate-based Z-scheme photocatalytic system under natural solar light

作者：Wang, Jiajia; Chen, Hui; Tang, Lin^*; Zeng, Guangming^*; Liu, Yutang; Yan, Ming; Deng, Yaocheng; Feng, Haopeng; Yu, Jiangfang; Wang, Longlu

来源：Science of the Total Environment, 2018, 639: 1462-1470.

DOI：10.1016/j.scitotenv.2018.05.258

• Antibiotics removal
• Silver phosphate
• Z-scheme system
• Anti-photocorrosion
• Natural solar light

Photocatalytic degradation is an alternative method to remove pharmaceutical compounds from water, however it is hard to achieve efficient rate because of the low efficiency of photocatalysts. In this study, an efficient Z-Scheme photocatalyst was constructed by integrating graphitic carbon nitride (CN) and reduced graphene oxide (rGO) with AP via a simple facile precipitation method. Excitedly, ternary AP/rGO/CN composite showed superior photocatalytic and anti-photocorrosion performances under both intense sunlight and weak indoor light irradiation. NOF can be completely degraded in only 30 min and about 85% of NOF can be mineralized after 2 h irradiation under intensive sunlight irradiation. rGO could work not only as a sheltering layer to protect AP from photocorrosion but also as a mediator for Z-Scheme electron transport, which can protect AP from the photoreduction. This strategy could be a promising method to construct photocatalytic system with high efficiency for the removal of antibiotics under natural light irradiation.

• 出版日期2018-10-15
• 单位湖南大学