Activated Carbons Prepared through H3PO4-Assisted Hydrothermal Carbonisation from Biomass Wastes: Porous Texture and Electrochemical Performance

作者：Quesada Plata Fabian; Ruiz Rosas Ramiro; Morallon Emilia; Cazorla Amoros Diego^*

来源：ChemPlusChem, 2016, 81(12): 1349-1359.

DOI：10.1002/cplu.201600412

• biomass
• carbon
• hydrothermal treatments
• sustainable chemistry
• supercapacitors

Hydrothermal treatment of biomass in the presence of phosphoric acid is proposed for the production of activated carbons (ACs). Interestingly, H3PO4 promotes the fixation of carbon atoms in the solid during hydrothermal treatment, which renders higher preparation yields than those of the conventional impregnation method. Upon carbonisation of the resulting hydrochars at 450 degrees C, a notable development of porosity is achieved by using a low amount and concentration of phosphoric acid; these conditions are not adequate for conventional activation. The viability of this process for the sustainable production of ACs has been successfully checked in four biomasses of different composition and structures, and ACs of surface areas above 2000 m(2)g(-1) and tuneable pore size distribution have been obtained. Electrochemical characterisation of ACs prepared at 750 degrees C in 1m H2SO4 demonstrates that capacitances of approximately 150 Fg(-1) with acceptable rate performance can be obtained through this simple method.

• 出版日期2016-12