A polylinear regression model taking into account the cross effects of the structure and temperature in the reactions of phenyloxirane with benzoic acids, catalyzed by pyridines: Evidence of the isoparametricity phenomenon

作者：Shpan'ko I V^*; Sadovaya I V

来源：Russian Journal of Applied Chemistry, 2013, 86(8): 1256-1261.

DOI：10.1134/S107042721308017X

The joint effect of the structure and temperature on the rate of the reactions of phenyloxirane with Y-substituted benzoic acids in acetonitrile, catalyzed by X-substituted pyridines, was studied. A polylinear regression model that adequately describes the effects of cross-varied factors was calculated. Owing to intensive interaction of the effects of the substituents X and temperature, experimental evidence for the isoparametricity phenomenon was obtained.

• 出版日期2013-8