An Oxygen/Chlorine Double-Capped Praseodymium Tetramer Cluster Complex with Thiazole

作者：Dannenbauer Nicole; Mueller Buschbaum Klaus

来源：Zeitschrift fur Anorganische und Allgemeine Chemie, 2013, 639(15): 2737-2740.

DOI：10.1002/zaac.201300263

• Cluster complex
• Thiazole
• Praseodymium
• Crystal structure

A tetramer cluster complex of the formula [Pr4Cl10(OH)(2)(thz)(8)(H2O)(2)] was prepared constituted by two edge sharing metal triangles coordinated by thiazole (thz) and chloride ligands bent together by opposing (3)-hydroxide and chloride capping for both triangles. The tetramer is the first thiazole complex of a lanthanide ion and shows a previously unknown symmetric capping mode. It co-crystallizes with an anhydrous dimeric complex of the formula [Pr2Cl6(thz)(8)] in equal amounts.

• 出版日期2013-12