Preparation and reactivity of a dinitrogen-bridged dimolybdenum-tetrachloride complex

作者:Arashiba Kazuya; Kuriyama Shogo; Nakajima Kazunari; Nishibayashi Yoshiaki*
来源:Chemical communications, 2013, 49(95): 11215-11217.
DOI:10.1039/c3cc46946h

摘要

A dinitrogen-bridged dimolybdenum-tetrachloride complex is prepared and reduced with Super-Hydride (LiBHEt3) to afford the corresponding dimolybdenum-dinitrogen complex together with the formation of molecular dihydrogen. This reaction proceeds via the ligand exchange of the coordinated dihydrogen generated in situ with molecular dinitrogen.

  • 出版日期2013