Direct Dehydrative Esterification of Alcohols and Carboxylic Acids with a Macroporous Polymeric Acid Catalyst

作者:Minakawa Maki; Baek Heeyoel; Yamada Yoichi M A*; Han Jin Wook; Uozumi Yasuhiro
来源:Organic Letters, 2013, 15(22): 5798-5801.
DOI:10.1021/ol4028495

摘要

A macroporous polymeric acid catalyst was prepared for the direct esterification of carboxylic acids and alcohols that proceeded at 50-80 degrees C without removal of water to give the corresponding esters with high yield. Flow esterification for the synthesis of biodiesel fuel was also achieved by using a column-packed macroporous acid catalyst under mild conditions without removal of water.

  • 出版日期2013-11-15