Alkyldiamine bis(selenocyanato)cadmium(II) complexes: Synthesis, Cd-113, Se-77, N-15 and C-13 NMR spectroscopy and X-ray structure of a 2D metal-organic framework

作者：Fettouhi Mohammed; Al Maythalony Bassem A; Shaikh M Nasiruzzaman; Wazeer Mohammed I M; Isab Anvarhusein A^*

来源：Polyhedron, 2011, 30(7): 1262-1266.

DOI：10.1016/j.poly.2011.02.008

• Cadmium(II) complexes
• Selenocyanate
• Ethylenediamine
• Solid state NMR
• Cd-113 NMR
• X-ray structure

Complexes of cadmium(II)-selenocyanate with several alkyldiamine ligands have been synthesized and characterized by IR, Cd-113, (77)se, N-15 and C-13 NMR spectroscopy. The X-ray structure of the complex [Cd(SeCN)(2)-en] reveals two non-equivalent metal ion centers, both with a distorted octahedral geometry. The combined bridging modes of selenocyanate and ethylenediamine with the blocking mode of a chelating ethylenediamine generate a 2D metal-organic framework.

• 出版日期2011-4-27
• 单位中国石油大学（北京）