Decanuclear Copper Framework Supported by a Tripodal Adenine Ligand

作者:Mishra Ashutosh Kumar; Verma Sandeep*
来源:Inorganic Chemistry, 2010, 49(8): 3691-3693.
DOI:10.1021/ic100254t

摘要

This Communication describes the synthesis, crystal structure, and magnetic properties of a unique decanuclear copper complex of a tripodal adenine ligand built around a phenyl ring core. This complex comprises two mu(4)-oxo tetranuclear copper(II) units of the type Cu(4)OCl(6)L(4), bridged together by two pentacoordinated copper centers. Variable-temperature magnetic susceptibility data reveal the possibility of interaction between copper sites.

  • 出版日期2010-4-19