A flexible approach to hexahydronaphthalene-1-carboxylates

作者：Li Zhi; Alameda Angulo Celia; Quiclet Sire Beatrice; Zard Samir Z^*

来源：Tetrahedron, 2011, 67(51): 9844-9852.

DOI：10.1016/j.tet.2011.09.103

• Hexahydronaphthalene-1-carboxylate
• Nitroalkenes
• Favorskii rearrangement
• Claisen rearrangement

A flexible approach to hexahydronaphthalene-1-carboxylates based on the Favorskii rearrangement of 1,1-dichloro bicyclo[5.4.0]undec-5-en-2-ones has been devised. 1,1-Dichloro bicyclo[5.4.0]undec-5-en-2-ones can be prepared from readily available cyclohexanones by a short sequence.

• 出版日期2011-12-23