A family of ordered mesoporous carbons derived from mesophase pitch using ordered mesoporous silicas as templates

作者：Cao Liang; Kruk Michal^*

来源：Adsorption, 2010, 16(4-5): 465-472.

DOI：10.1007/s10450-010-9248-8

• Ordered mesoporous carbon
• Templated synthesis
• Ordered mesoporous silica
• Mesophase pitch
• High-surface-area solid

A variety of ordered mesoporous carbons (OMCs) were synthesized using ordered mesoporous silicas (OMSs) as hard templates and the mesophase pitch (MP) as a carbon precursor. The synthesis included the mixing of OMS with MP, the infiltration of OMS with MP at 450-550 A degrees C and the carbonization of MP in OMS/MP composite followed by the dissolution of the OMS template. OMCs with structures of two-dimensional hexagonal arrays of nanorods and three-dimensional arrays of nanospheres were obtained through the replication of silica templates, including large-pore SBA-15, KIT-6, large-pore FDU-12 and SBA-16. In particular, 2-D hexagonal array of carbon nanorods (CMK-3 carbon) with (100) interplanar spacing of similar to 13 nm as well as an array of carbon nanospheres arranged in the face-centered cubic structure with the unit-cell parameter of 33 nm were successfully prepared. The specific surface areas of the resulting carbons were up to 400 m(2)/g, and the total pore volumes were up to 0.43 cm(3)/g, with the highest values achieved when the MP infiltration temperature was 500 A degrees C. The OMCs exhibited narrow mesopore size distributions. As inferred from XRD, the frameworks of OMCs featured semi-graphitic structures even though moderate carbonization temperature (850 A degrees C) was employed.

• 出版日期2010-10