Design of Ionic Liquid 3-Methyl-1-sulfonic Acid Imidazolium Nitrate as Reagent for the Nitration of Aromatic Compounds by in Situ Generation of NO2 in Acidic Media

作者:Zolfigol Mohammad A*; Khazaei Ardeshir; Moosavi Zare Ahmad R; Zare Abdolkarim; Kruger Hendrik G; Asgari Zhila; Khakyzadeh Vahid; Kazem Rostami Masoud
来源:Journal of Organic Chemistry, 2012, 77(7): 3640-3645.
DOI:10.1021/jo300137w

摘要

3-Methyl-1-sulfonic acid imidazolium nitrate ([Msim]NO3) as a new Bronsted acidic ionic liquid and nitrating agent was prepared and used for the efficient nitration of aromatic compounds (even aniline derivatives). The dramatic effect of this reagent by in situ generation of nitrogen dioxide as a radical on aromatic compounds to give nitroarenes has been studied.

  • 出版日期2012-4-6