Microstructure, interfacial interactions, and rheological properties of PC/AES/montmorillonite composites

作者：Liu, Bo; Zhang, Yong; Wan, Chaoying; Zhang, Yinxi; Su, Yu; Ji, Jiliang

来源：Journal of Macromolecular Science Part B-Physics, 2006, 45(6): 1159-1169.

DOI：10.1080/00222340600974192

• rheology
• microstructure
• interfacial interaction
• PC
• AES
• OMMT

Polycarbonate (PC) and acrylonitrile-EPDM (ethylene/propylene/diene elastomer) styrene ter-polymer (AES) blends and PC/AES/organically modified montmorillonite (OMMT) composites were prepared at 20%, 40%, 50% by weight of AES and 3% by weight of OMMT. The microstructure, interfacial interactions, and rheological properties of the PC/AES blends and PC/AES/OMMT composites were studied systematically. X-ray diffractometer (XRD) results reveal that the AES is easier to intercalate into OMMT than PC, and the content of AES has a little effect on the interlayer distance of OMMT. Wetting coefficient calculation indicates that OMMT distributes primarily at the interface of the polymer blend. Field emission scanning electron microscope (FE-SEM) observation indicates that the phase morphology of PC/AES blends and PC/AES/OMMT composites is not influenced by the OMMT. However, linear rheological properties suggest that the addition of OMMT has a great effect on the linear rheological property.

• 出版日期2006-11
• 单位上海交通大学