Alternate Multilayer Films of Poly(vinyl alcohol) and Exfoliated Graphene Oxide Fabricated via a Facial Layer-by-Layer Assembly

作者：Zhao, Xin; Zhang, Qinghua^*; Hao, Yanping; Li, Yingzhi; Fang, Ying; Chen, Dajun

来源：Macromolecules, 2010, 43(22): 9411-9416.

DOI：10.1021/ma101456y

• MECHANICAL-PROPERTIES
• AQUEOUS DISPERSIONS
• DOUBLE HYDROXIDE
• GRAPHITE OXIDE
• THIN-FILMS
• POLY(4-VINYLPYRIDINE)
• NANOPLATELETS
• DELAMINATION
• NANOSHEETS
• REDUCTION

Despite great recent progress with graphene based materials, the development of strong and cost efficient multifunctional graphene filled polymer composites has not yet to be achieved A key challenge in the fabrication of nanoplatelet filled polymer composites is the ability to realize the nanometer-level dispersion and the planar orientation of nanosheets in polymer matrices In this report, ultrathin multilayer (PVA/GO)(n) films were successfully fabricated by bottom-up layer by-layer (LBL) assembly of poly(vinyl alcohol) (PVA) and exfoliated graphene oxide (GO), in which exfoliated GO nanosheets were used as the building blocks Typical tapping-mode atomic force microscope (AFM) and field emission scanning electron microscope (FESEM) Images demonstrate an ordered arrangement of organic and inorganic layers A significant enhancement of mechanical properties has been achieved, that is a 98 7% improvement of elastic modulus (E-r) and a 240 4% Increase of hardness This may be attributed to the well-defined layered architecture with high degree of planar orientation and nanolevel assemblies of GO nanosheets in the polymer matrices

• 出版日期2010-11-23
• 单位东华大学