Monitoring the stepwise assembly of a 3-D framework from a supramolecular lanthanoid synthon by in situ infrared spectroscopy

作者：Andrews Philip C; Gee William J; Junk Peter C^*; Krautscheid Harald; MacLellan Jonathan G

来源：Chemical Communications, 2010, 46(32): 5948-5950.

DOI：10.1039/c0cc00949k

Construction of a 3-D supramolecular network from [Ln(cpb)(3)(H(2)O)(2)] (Ln = Nd, Tb; Hcpb = 1-(4-cyanophenyl)1,3-butanedione) by sequential displacement of a coordinated water by DMF, dimerisation by reciprocal hydrogen bonding in solution and pi-pi stacking and interdigitation of nitriles has been monitored by in situ fourier transform infrared spectroscopy.

• 出版日期2010