A regression model for calculating the boiling point isobars of tetrachloromethane-based binary solutions

作者：Preobrazhenskii M P^*; Rudakov O B

来源：Russian Journal of Physical Chemistry, 2016, 90(1): 109-112.

DOI：10.1134/S0036024416010234

• isobar
• boiling point
• regression
• binary solutions
• tetrachloromethane
• azeotropy
• hydrophobicity criterion

A regression model for calculating the boiling point isobars of tetrachloromethane-organic solvent binary homogeneous systems is proposed. The parameters of the model proposed were calculated for a series of solutions. The correlation between the nonadditivity parameter of the regression model and the hydrophobicity criterion of the organic solvent is established. The parameter value of the proposed model is shown to allow prediction of the potential formation of azeotropic mixtures of solvents with tetrachloromethane.

• 出版日期2016-1