Analysis of crystals of retrograded starch with sharp X-ray diffraction peaks made by recrystallization of amylose and amylopectin

作者：Lian, Xijun^*; Cheng, Kaili; Wang, Danli; Zhu, Wei; Wang, Xueqing

来源：International Journal of Food Properties, 2018, 20(sup3): S3224-S3236.

DOI：10.1080/10942912.2017.1362433

• Sweet potato amylose
• Amylopectin
• Interaction
• X-ray diffraction
• Crystal

Retrogradation is a common occurrence of starchy food and many methods have been tried to retard it. Uncovering the crystalline structure of retrograded starch provides us the necessary information to get an effective method. In this paper, the crystals of retrograded sweet potato starch with sharp X-ray diffraction peaks were obtained by blending sweet potato amylose and amylopectin with narrow distribution of molecular weight. The 2 angles of those crystals were at 14.7 degrees, 20.7 degrees, 24.3 degrees, 26.5 degrees, and 29.9 degrees. Intervals between two branched chains in retrograded amylose were 0.606, 0.348nm, and in retrograded amylopectin 0.336nm. A possible mechanism for the formation of those crystals was proposed based on analyzing H-1 NMR, C-13 NMR, X-ray diffraction, and differential scanning calorimeter of those samples. Cocrystallized amylose and amylopectin was necessary to prepare crystals of retrograded starch. More ordered arrangements exist in retrograded starch of sweet potato amylose and amylopectin.

• 出版日期2018
• 单位天津商业大学