A novel chemiluminescence enhanced method for determination of putrescine in shrimp based on the luminol-[Ag(HIO6)(2)](5-) reaction

作者：Chen, Peiyun^*; Sun, Hanwen; Wang, Xianyou; Pang, Yanping; Li, Bin

来源：Analytical Methods, 2016, 8(5): 1151-1156.

DOI：10.1039/c5ay02596f

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A novel chemiluminescence (CL) method to determine putrescine was proposed based on the enhanced effect of putrescine on CL emission of the [Ag(HIO6)(2)](5-) -luminol system. The enhanced degree of CL emission was proportional to the putrescine concentration. Under optimal conditions, there was a linear relationship between the increase in CL intensity and the putrescine concentration over a range of 4.0 x 10(-8) to 4 x 10(-6) g mL with a detection limit (3s) of 1.76 x 10(-8) g mL(-1). The relative standard deviation (RSD) was 3.2% for 11 replicate determinations of 1.0 x 10(-6) g mL(-1) putrescine. The proposed CL reaction systems had potential capability for residue analysis of studied analytes in food samples. A possible mechanism of CL emission and enhanced effect was also suggested.

• 出版日期2016
• 单位河北大学