An Unconventional Synthesis of Dibromophosphines

作者:Wang Lili; Zhang Lujun; Shi Hanyu; Duan Zheng*; Mathey Francois
来源:Synlett, 2013, 24(15): 2006-2008.
DOI:10.1055/s-0033-1339548

摘要

Dibromophosphines, RPBr2, are obtained by reaction of tetrabromomethane with 7-substituted 7-phosphanorbornenes in toluene at ca. 100 degrees C. The phosphanorbornenes are obtained in situ by cycloaddition of N-phenylmaleimide with 1-substituted 3,4-di-methylphospholes. The overall reaction sequence shows a good compatibility with functional groups.

  • 出版日期2013-9-17
  • 单位南阳理工学院; 郑州大学

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