科研之友
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摘要
Novel biphasic structured in situ silica filled natural rubber composites were focused on their strain-induced crystallization (SIC) behavior from the viewpoint of morphology. The composites were prepared by in situ silica filling in natural rubber (NR) latex using a sol-gel reaction of tetraethoxysilane. Simultaneous time-resolved wide-angle X-ray diffraction and tensile measurements revealed a relationship between the characteristic morphology and tensile stress-strain properties of the composites associating with the SIC. Results showed stepwise SIC behaviors of NR-based composites for the first time. Pure rubber phases in the biphasic structure were found to afford highly oriented amorphous segments and oriented crystallites. The generated crystallites worked as reinforcing fillers together with the in situ silica to result in high tensile stresses of the composites. The observed characteristics are useful for understanding a role of filler network in the reinforcement of rubber.
- 出版日期2014-3
