Nanocrystalline Pt-doped TiO2 thin films prepared by spray pyrolysis for hydrogen gas detection

作者：Patil Lalchand A^*; Suryawanshi Dinesh N; Pathan Idris G; Patil Dhanashri G

来源：Bulletin of Materials Science, 2014, 37(3): 425-432.

DOI：10.1007/s12034-014-0705-y

• Spray pyrolysis techniques
• TiO2 thin films
• hydrogen gas response

Nanostructured pure and Pt-doped TiO2 thin films were prepared by chemical spray pyrolysis technique. Aqueous solution of TiCl3 center dot 6H(2)O (0.01 M) was chosen as the starting solution for the preparation of pure TiO2 thin film. Aqueous solutions of PtCl6 center dot 6H(2)O (0.01 M) and TiCl3 center dot 6H(2)O (0.01 M) were mixed in volume % of 1 : 99, 2.5 : 97.5 and 5 : 95 respectively to obtain Pt-doped TiO2 thin films. The solutions were sprayed onto quartz substrate heated at 350 degrees C temperature to obtain the films. These thin films were fired for one hour at 550 degrees C. The sensing performance of these films was tested for various gases such as LPG, H-2, CO2, ethanol, NH3 and CI2 (1000 ppm). The Pt-doped TiO2 (1 : 99) was observed to be most sensitive (572) to H-2 at 400 C with high selectivity against other gases. Its response time was short (10 s) and recovery was also fast (14 s). To understand the reasons behind the gas-sensing performance of the films, their structural and microstructral properties were studied using X-ray diffraction and electron microscopy (FE-SEM and TEM), respectively. Thicknesses of all these samples were determined using Surface Profiler. The results are interpreted.

• 出版日期2014-5