A room temperature solution-phase method to synthesize beta-Ni(OH)(2) nanoneedles

作者:Wang Wenzhong*; Lu Baoli; Wang Yan; Zhang Ning; Zhang Guling
来源:Materials Letters, 2011, 65(11): 1591-1594.
DOI:10.1016/j.matlet.2011.02.085

摘要

A simple room temperature solution-phase method has been employed to synthesize beta-Ni(OH)(2) nanoneedles in the presence of a suitable cationic surfactant cetyltrimethylammonium bromide for the first time. The chemical composition and morphology of the as-prepared beta-Ni(OH)(2) nanoneedles were characterized by X-ray powder diffraction and transmission electron microscopy. The effect of surfactant and NH4OH on the morphology and size of beta-Ni(OH)(2) nanoparticles was discussed in detail. The growth mechanism of the as-synthesized nanoneedles was discussed based on the experimental results. The results indicate that the binding between CTAB and beta-Ni(OH)(2) crystal nuclei inhibits crystal growth randomly and favors needle-like single crystal growth with their preferred facets.

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