Organometallic Strategies for the Synthesis of Conjugated Oligomers

作者：Babudri Francesco; Farinola Gianluca M; Naso Francesco^*

来源：Synlett, 2009, 2009(17): 2740-2748.

DOI：10.1055/s-0029-1217978

• arylations
• oligomerization
• boron
• tin
• cross-coupling

In this account we report on our contribution to the synthesis of conjugated oligomers with defined Structures. The targets of our work are oligoenes, oligophenylenevinylenes, also with fluorinated vinylene units, oligophenylenes, and oligomers with thiophene-arylene or thiophene-anthraquinone units. The synthetic strategies developed in our research group are based oil transition-metal-catalyzed coupling reactions. This report is organized according to the synthetic methodologies used (use of vinylsilanes, Stille cross-coupling, copper-promoted homocoupling, and Suzuki-Miyaura cross-coupling) rather than oil the basis of the target molecules obtained.
1 Introduction
2 The Use of Vinylsilanes in the Synthesis of Polyenes and Oligophenylenevinylenes
3 Stille Cross-Coupling
4 Copper-Promoted Homocoupling Reaction for the Synthesis of fluorinated Oligophenylenes
5 Suzuki-Miyaura Cross-Coupling
6 Conclusions

• 出版日期2009-10-21