Allenylidene Complexes Based on Pentacenequinone

作者：Strinitz Frank; Waterloo Andreas; Tucher Johannes; Huebner Eike; Tykwinski Rik R; Burzlaff Nicolai^*

来源：European Journal of Inorganic Chemistry, 2013, 2013(29): 5181-5186.

DOI：10.1002/ejic.201300759

• Ruthenium
• Allenes
• Density functional calculations
• Fused ring systems

Stable ruthenium-allenylidene complexes based on pentacenequinone have been synthesized. The complexes show an electronic absorption in the NIR region that arises from forbidden MLCT transitions, as explained by DFT calculations. The crystal structure reveals promising features for the formation of metal-influenced organic FETs.

• 出版日期2013-10-1