Anthroxyl-based biradical: toward the construction of highly stable multi-spin systems

作者:Hirao Yasukazu*; Konishi Akihito; Kubo Takashi*
来源:Organic Chemistry Frontiers, 2017, 4(5): 828-833.
DOI:10.1039/c7qo00130d

摘要

A new two-spin system having two anthroxyl radicals at the 9,10-positions of anthracene was found to be stable even after exposing it to refluxing polar-protic solvents. This stability might be derived from the spin delocalization as well as the steric protection of the spin center by the orthogonally oriented anthracene.

  • 出版日期2017-5-1