Doping potassium ions in silver cyanide complexes for green luminescence

作者：Liu, Xi^*; Li, Lin; Yang, Yun-Zhi; Huang, Kun-Lin

来源：Dalton Transactions, 2014, 43(10): 4086-4092.

DOI：10.1039/c3dt53219d

• ENCAPSULATED ACETYLIDE DIANION
• NEGATIVE THERMAL-EXPANSION
• COORDINATION POLYMERS
• CRYSTAL-STRUCTURE
• DOUBLE SALTS
• SUPRAMOLECULAR COMPLEXES
• ARGENTOPHILICITY
• SPECTROSCOPY
• ADDUCTS
• MAGNETS

Doping potassium ions in silver cyanide complexes leads to two heterometallic silver-potassium cyanide complexes, namely, [Me4N](2)[KAg3(CN)(6)] (1) with a typical NaCl-type framework containing distinct ligand-unsupported argentophilic interactions, and [Ag-3(H2O)(3)][K(CN)(2)](3) (2) with an unprecedented 3-D (4,4,6,6)-connected framework formed by unique [Ag-3(H2O)(3)] clusters connecting concave-convex (2)(infinity)[K(CN)(2)] layers. The two complexes exhibit green luminescence, and the relationships between their structures and photoluminescence, as well as the regulating effect on the luminescence by doping of potassium ions are well investigated via density functional theory analysis.

• 出版日期2014
• 单位重庆师范大学