Diethyl 2-{[2-(trifluoromethyl)anilino]methylidene}propanedioate

作者:Garudachari B; Isloor Arun M; Satyanarayan M N; Gerber Thomas; Hosten Eric; Betz Richard*
来源:Acta Crystallographica Section E-Structure Reports Online, 2012, 68: O514-U1655.
DOI:10.1107/S1600536812002590

摘要

The title compound, C15H16F3NO4, is an N-substituted derivative of ortho-trifluoromethylaniline featuring a twofold Michael system. The least-squares planes defined by the atoms of the phenyl ring and the atoms of the Michael system enclose an angle of 15.52 (5)degrees. Apart from classical intramolecular N-H center dot center dot center dot O and N-H center dot center dot center dot F hydrogen bonds, intermolecular C-H center dot center dot center dot O contacts are observed, the latter connecting the molecules into chains along [110]. The shortest intercentroid distance between two aromatic systems is 3.6875 (9) angstrom.

  • 出版日期2012-2