Branched charge-transfer chromophores featuring a 4,5-dicyanoimidazole unit

作者:Bures Filip*; Kulhanek Jiri; Mikysek Tomas; Ludvik Jiri; Lokaj Jan
来源:Tetrahedron Letters, 2010, 51(15): 2055-2058.
DOI:10.1016/j.tetlet.2010.02.067

摘要

Six branched and stable push-pull chromophores featuring 4,5-dicyanoimidazole as an acceptor moiety, an N,N-dimethylamino group as a donor and various pi-conjugated linkers are reported. Systematic extension of the pi-linker revealed that the optical and electrochemical properties of A-pi-D chromophores are mainly affected by the nature of the pi-conjugated backbone (length and planarity) as well as by the number of appended donors.

  • 出版日期2010-4-14