An improved approach for measuring Henry's law coefficients of atmospheric organics

作者：Kish, J. Duncan; Leng, Chunbo; Kelley, Judas; Hiltner, Joseph; Zhang, Yunhong; Liu, Yong^*

来源：Atmospheric Environment, 2013, 79: 561-565.

DOI：10.1016/j.atmosenv.2013.07.023

• Henry's law constant
• Bubble column technique
• Infrared gas cell
• Temperature dependence
• Ionic strength effect

In this work, we present an improved method for Henry's law constant, KH, measurements by coupling a bubble column system with a gas cell/infrared spectrometer. To demonstrate the feasibility of this approach, we measured ICH of atmospheric organics from three different classes, namely, toluene (hydrocarbon), sec-butylamine (amine), and cineole (ether). We also reported temperature and ionic strength effects on the ICH values of sec-butylamine for the first time. As shown in this work, the method is highly capable of determining KH of atmospheric organic species regardless the presence of heteroatoms and the occurrence of hydration in water. It is very versatile, easy to use, reliable, and efficient. It is also well-suited for undergraduate students to conduct environmental chemical science research during academic semesters.

• 出版日期2013-11
• 单位北京理工大学