Adhesion of Poly(phenylene sulfide) Resin with Polymeric Film of Triazine Thiol on Aluminum Surface Modified by Anodic Oxidation

作者：Chung Eun Hyuk; Jang Eun Kyung; Hong Tae Eun; Kim Jong Pil; Kim Hyun Gyu; Jin Jong Sung; Hyun Myung Ho; Shin Dong Su; Bae Jong Seong^*; Jeong Euh Duck

来源：Journal of Biomedical Nanotechnology, 2015, 11(1): 157-164.

DOI：10.1166/jbn.2015.2027

• Triazine Thiol
• Aluminum anodic Oxidation
• Al-PPS Resin
• Li Ion Secondary Batteries
• Peel Strength

Various surface modifications have been applied to improve the adhesion properties of aluminum for the cap plate and sealing quality of electrolyte on Li ion batteries. In this study, we have tried to find the effective condition for the polymerization of triazine thiols (TT) on modified aluminum surfaces by anodic aluminum oxide. Characterization of polymerized films on aluminum was explored by scanning electron microscopy, X-ray photoelectron spectroscopy, and secondary ion mass spectroscopy analysis. Scanning electron microscopy results reveal that meaningful roughness was formed on aluminum surfaces by anodic oxidation. Secondary ion mass spectroscopy analysis results represent that the peel strength was found to depend on film thickness and the composition of the adhesion layer. As a result, Al/PPS (polyphenylene sulfide) resin assemblies developed in this study have superior adhesive property. Therefore, these assemblies might be a viable candidate for a sealing technique for Li ion batteries.

• 出版日期2015-1