A hexanuclear manganese(II) complex: synthesis, characterization and catalytic activity toward organic sulfide oxidation

作者：Najafpour Mohammad Mandi^*; Amini Mojtaba; Holynska Malgorzata; Zare Maryam; Amini Emad

来源：New Journal of Chemistry, 2014, 38(10): 5069-5074.

DOI：10.1039/c4nj01159g

Herein we report on the synthesis and characterization of a hexanuclear [Mn-6(II)] wheel-like assembly with naphthalene-1,8-dicarboxylate and 1,10-phenanthroline as ligands. Overall antiferromagnetic behavior of the magnetic properties is observed. The complex acts as a catalyst toward organic sulfide oxidation in the presence of H2O2 with good selectivity (98-100%).

• 出版日期2014-10