A Membrane-Free Ferrocene-Based High-Rate Semiliquid Battery

作者：Ding Yu; Zhao Yu; Yu Guihua

来源：Nano Letters, 2015, 15(6): 4108-4113.

DOI：10.1021/acs.nanolett.5b01224

• Energy storage
• ferrocene
• Li redox batteries
• power density
• sustainable chemistry

We report here a ferrocene-based membrane-free, high-rate semiliquid battery that takes advantage of a highly soluble ferrocene/ferrocenium redox couple in nonaqueous phase. The designed battery exhibits stable capacity retention up to 94% of theoretical capacity of ferrocene (145 mAh g(-1)) at a broad current rate up to 60 C owing to rapid mass transport in a liquid phase and fast redox kinetics. The diffusion coefficient and the standard reaction constant are determined to be in the order of 10(-6) cm(2) s(-1) and 10(-1) cm s(-1), respectively, orders of magnitude greater than those in a solid-phase electrode and those in conventional redox flow batteries. Additionally, the battery demonstrates power density and energy density exceeding 1400 W L-1 and 40 Wh L-1, respectively, and stable cyclability with capacity retention of similar to 80% for 500 cycles. Compared with state-of-the-art energy storage technologies such as Li-ion batteries or conventional redox flow batteries, the proposed liquid battery shows the potential to be an efficient energy storage system with exceptionally high power and reasonable energy density.

• 出版日期2015-6