High-yield nanosized (Si) AlPO-41 using ethanol polarity equalization and co-templating synthesis approach

作者：Majano Gerardo; Raltchev Kolio; Vicente Aurelie; Mintova Svetlana^*

来源：Nanoscale, 2015, 7(13): 5787-5793.

DOI：10.1039/c4nr07272c

Control of the crystallite dimensions of the microporous aluminophosphate AlPO-41 (AFO-type framework structure), and the Si-containing analogue SAPO-41, was attained down to the nanometer scale under stable hydrothermal conditions. The combined application of a tetraalkylammonium co-template (tetrapentylammonium hydroxide) along with an amine structure directing agent (n-dipropylamine) stabilized through the use of ethanol in the initial suspension enables a crystallization medium, which remains homogeneous throughout the entire synthesis. As a direct consequence of the optimized homogeneity of the suspension, the AFO-type microporous nanocrystals (AlPO-41 and SAPO-41) with a size in the range of 30-500 nm with yields surpassing 50% are obtained. The feasibility to obtain nanosized AlPO-41 and SAPO-41 crystals using ethanol as a polarity equalizing agent, resulting in a scalable hydrothermal synthesis from non-colloidal starting mixtures without the use of other assisting methods, is presented.

• 出版日期2015