Size-matched recognition of large anions by cyanostar macrocycles is saved when solvent-bias is avoided

作者:Qiao Bo; Anderson Joseph R; Pink Maren; Flood Amar H*
来源:Chemical Communications, 2016, 52(56): 8683-8686.
DOI:10.1039/c6cc03463b

摘要

The size-dependent recognition of large anions by shape-persistent macrocycles is poorly understood. To address this shortcoming, we created a bulky cyanostar that only forms 1 : 1 complexes and show the affinities best follow the expectations of size matching but only when solvent bias is removed.

  • 出版日期2016