{[Cu3Lu2(ODA)(6)(H2O)(6)]center dot 10H(2)O}(n): the first heterometallic framework based on copper(II)/lutetium(III) for the catalytic oxidation of olefins and aromatic benzylic substrates

作者：Cancino P; Paredes Garcia V; Torres J; Martinez S; Kremer C; Spodine E^*

来源：Catalysis Science & Technology, 2017, 7(21): 4929-4933.

DOI：10.1039/c7cy01385j

The catalytic performance of the novel framework {[Cu3Lu2(ODA)(6)(H2O)(6)]center dot 10H(2)O}(n) was tested in the oxidation of alkenes and benzylic hydrocarbons, using tert-butyl hydroperoxide (TBHP) and molecular oxygen (O-2) as oxidants. Excellent conversions were obtained with O-2 under solvent-free conditions, in the absence of a co-catalyst, for cyclohexene (95%) and for cumene (91%).

• 出版日期2017-11-7