A new 3-fold interpenetrated metal-organic framework (MOF) based on trinuclear zinc(II) clusters as secondary building unit (SBU)

作者：Liu, Yong-Liang; Yue, Ke-Fen^*; Shan, Bing-Hui; Xu, Li-Li; Wang, Cheng-Jun; Wang, Yao-Yu

来源：Inorganic Chemistry Communications, 2012, 17: 30-33.

DOI：10.1016/j.inoche.2011.12.008

• Metal-organic framework (MOF)
• The secondary building unit (SBU)
• Interpenetration

A new metal-organic framework (MOF), [Zn-3(4,4'-ADB)(3)(BIB)(2)](n) (1) has been synthesized based on mixed bridging ligands BIB and 4,4'-ADB (BIB = 1,4-bis(2-methyl-imidazol-1-yl) butane, 4,4'-ADB = azobenzene-4,4'-dicarboxylica acid). This MOF is a 3D structure with trinuclear zinc(II) clusters as SBU. The trinuclear zinc (II) clusters of line style feature zincs in two tetrahedral and one octahedral coordination environments. The MOF exhibits a 3-fold interpenetrated framework with 3(6).4(18).5(3).6 topology, which reduces the effective void but stabilizes the compound.

• 出版日期2012-3
• 单位西北大学