Nonporous homochiral copper-based coordination polymers for enantioselective recognition and electrocatalysis

作者：Zhang, Guangju; Zhao, Fangfang; Hu, Hailiang^*; Li, Hao; Dong, Huan; Han, Xiao; Huang, Hui

来源：Inorganic Chemistry Communications, 2014, 40: 31-34.

DOI：10.1016/j.inoche.2013.11.031

• Nonporous
• Homochiral coordination polymers
• Chiral catalysis
• Enantioselective recognition

A pair of nonporous enantiomers [Cu(H2O)(bPY)(L-DBTA)]center dot H2O (L-1) and [Cu(H2O)(bPY)(D-DBTA)]center dot H2O (D-1)(L-DBTA) = (-)-dibenzoyl-L-tartaric acid, bpy = 4,4'-bipyridine) with interdigitated architecture possess excellent enantioselective recognition and electrocatalysis ability towards L- and/or D-tart.

• 出版日期2014-2
• 单位苏州大学