Asymmetric palladium-catalyzed hydrosilylation of styrenes using efficient chiral spiro phosphoramidite ligands

作者：Guo XX; Xie JH; Hou GH; Shi WH; Wang LX; Zhou QL^*

来源：Tetrahedron: Asymmetry , 2004, 15(14): 2231-2234.

DOI：10.1016/j.tetasy.2004.05.038

Asymmetric hydrosilylation of styrene derivatives with trichlorosilane in the presence of palladium complexes of chiral spiro phosphoramidites provided 1-aryl-1-silylalkanes as single regioisomers in high yields, which have been oxidized with hydrogen peroxide to give the corresponding chiral alcohols in up to 99.1% ee.

• 出版日期2004-7-26
• 单位南开大学; 华东理工大学