A novel ionic liquid for Li ion batteries - uniting the advantages of guanidinium and piperidinium cations

作者：Bucher Nicolas; Hartung Steffen; Arkhipova Maria; Yu Denis; Kratzer Philipp; Maas Gerhard; Srinivasan Madhavi; Hoster Harry E^*

来源：RSC Advances, 2014, 4(4): 1996-2003.

DOI：10.1039/c3ra46118a

We report on the synthesis and the properties of N,N,N',N'-tetramethyl-N '',N ''-pentamethyleneguanidinium bis(trifluoromethylsulfonyl)imide (PipGuan-TFSI). The cation of this novel ionic liquid combines guanidinium and piperidinium structural elements. We tested it for its viscosity, ion conductivity, and also for its thermal and electrochemical stability. Furthermore, a 0.5 M solution of lithium TFSI in PipGuan-TFSI was tested as an electrolyte for Li-ion batteries. These experiments included cycles of Li deposition/dissolution on stainless steel and (de) intercalation into/from LiFePO4 electrodes. The tests involving LiFePO4 cathodes were performed at various C-rates and temperatures for a better quantitative comparison to other electrolyte systems. We discuss in how far PipGuan-TFSI successfully combines the advantages of guanidinium and piperidinium ionic liquids for battery electrolyte applications.

• 出版日期2014