A bismuth-based fluorous metal-organic framework for efficient degradation of Congo red

作者：Kong, Ya-Jie; Han, Li-Juan^*; Fan, Lu-Tong; Kong, Fan-Zhen; Zhou, Xiao

来源：Journal of Fluorine Chemistry, 2016, 186: 40-44.

DOI：10.1016/j.jfluchem.2016.04.011

• Bismuth(III)
• Fluorous metal-organic framework
• Degradation
• Congo red

A new bismuth-based fluorous metal-organic framework, [Bi(OOCC6F5)(3)(C10H8N2)(H2O)(2)], (OOCC6F5 = pentafluorobenzoate, C10H8N2 =2,2'-bipyridine)(1) is synthesized by a hydrothermal method. Compound 1 crystalizes in the P2(1)/c space group, exhibiting a two-dimensional supramolecular architecture by intermolecular C-H center dot center dot center dot F-C interactions between the hydrogen atoms in 2,2'-bipyridine and fluorine atoms in adjacent perfluorophenyl rings. In addition, compound 1 shows excellent properties of degradation Congo red in the absence of UV-vis radiation. Moreover, adsorption kinetics study suggested that the adsorption of Congo red belongs to first-order reaction kinetics. Our results indicated that bismuth-based FMOFs could be promising candidates for the development of efficient degradation of organic dye.

• 出版日期2016-6
• 单位山东大学; 济宁学院