Hydrothermal in situ synthesis and characterization of Cu(II) complexes

作者:Weng Danfeng; Mu Weihua; Zheng Xiangjun; Fang Decal; Jin Linpei*
来源:Inorganic Chemistry, 2008, 47(4): 1249-1251.
DOI:10.1021/ic702107e

摘要

The hydrothermal in situ Cu(II)/2,3-pyrazine dicarboxylic acid reactions at 100 and 140 degrees C result in Cu(II) 3-hydroxy-2-pyrazinecarboxylate and oxalate complexes, respectively. This is the first example of a combination of experimental and theoretical study on in situ metal/ligand reactions under hydro- and solvothermal conditions.