Density, viscosity and electrical conductivity of AlCl3-amide ionic liquid analogues

作者:Liu, Chengyuan; Chen, Wenting; Wu, Zimo; Gao, Bingliang*; Hu, Xianwei; Shi, Zhongning; Wang, Zhaowen
来源:Journal of Molecular Liquids, 2017, 247: 57-63.
DOI:10.1016/j.molliq.2017.09.091

摘要

The density, viscosity and electrical conductivity of AlCl3-amide (amide = urea, acetamide, propionamide, butyramide) ionic liquid (IL) analogues with varied molar fractions of AICl(3) were measured at temperatures ranging from 313 K to 373 K. All the experimental values were fitted with the empirical equations. Meanwhile, the molar volume and molar conductivity of AlCl3-amide were also obtained. Based on the results, the difference in the properties of AlCl3-amide IL analogues are mainly attributed to the species of amide ligands, which have significant effects on complex structure, ionic interaction and hydrogen bonding of IL analogues.