Novel chiral and achiral NCN pincer complexes based on 1,3-Bis(1H-1,2,4-triazol-1-ylmethyl)benzene

作者：Diez Barra E^*; Guerra J; Lopez Solera I; Merino S; Rodriguez Lopez J; Sanehez Verdu P; Tejeda J

来源：Organometallics, 2003, 22(3): 541-547.

DOI：10.1021/om020764i

NCN pincer ligands based on 1,2,4-triazole and their corresponding palladium(II) complexes have been synthesized by the reaction of 1,3-bis(1H-1,2,4-triazol-1-ylmethyl)benzene derivatives with palladium(II) acetate. All compounds are ortho,ortho-metalated. Chiral complexes were obtained by using pincer ligands with substituents on the arms. The chiral complexes are conformationally rigid up to 150 degreesC.

• 出版日期2003-2-3