A Convenient Iron-Catalyzed Method for the Preparation of 1,2-Bis(trimethylsilyl)benzenes

作者：Bader Samuel L^*; Kessler Simon N; Wegner Hermann A

来源：Synthesis, 2010, (16): 2759-2762.

DOI：10.1055/s-0030-1258144

• Grignard reaction
• catalysis
• iron
• silicon
• metalation

A convenient iron-catalyzed method for the preparation of 1,2-bis(trimethylsilyl)benzenes is presented. Compared to the current procedures, low temperatures and toxic solvents are avoided, allowing large-scale preparation. Additionally, a variety of substituents are tolerated.

• 出版日期2010-8